Smallest Swiss Cross – Made of 20 Single Atoms

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20 bromine atoms positioned on a sodium chloride surface using the tip of an ato
20 bromine atoms positioned on a sodium chloride surface using the tip of an atomic force microscope at room temperature, creating a Swiss cross with the size of 5.6nm. The structure is stable at room temperature and was achieved by exchanging chlorine with bromine atoms. (Fig: Department of Physics, University of Basel)

The manipulation of atoms has reached a new level: Physicists were able to place 20 single atoms on a fully insulated surface at room temperature to form the smallest “Swiss cross”, thus taking a big step towards next generation atomic-scale storage devices.

Ever since the 1990s, physicists have been able to directly control surface structures by moving and positioning single atoms to certain atomic sites. A number of atomic manipulations have previously been demonstrated both on conducting or semi-conducting surfaces mainly under very low temperatures. However, the fabrication of artificial structures on an insulator at room temperature is still a long-standing challenge and previous attempts were uncontrollable and did not deliver the desired results.

In this study, an international team of researchers around Shigeki Kawai and Ernst Meyer from the Department of Physics at the University of Basel presents the first successful systematic atomic manipulation on an insulating surface at room temperatures. Using the tip of an atomic force microscope, they placed single bromine atoms on a sodium chloride surface to construct the shape of the Swiss cross. The tiny cross is made of 20 bromine atoms and was created by exchanging chlorine with bromine atoms. It measures only 5.6 nanometers square and represents the largest number of atomic manipulations ever achieved at room temperature.

New storage devices

Together with theoretical calculations the scientists were able to identify the novel manipulation mechanisms to fabricate unique structures at the atomic scale. The study thus shows how systematic atomic manipulation at room temperature is now possible and represents an important step towards the fabrication of a new generation of electromechanical systems, advanced atomic-scale data storage devices and logic circuits.

Original source:
Shigeki Kawai, Adam S. Foster, Filippo Federici Canova, Hiroshi Onodera, Shin-ichi Kitamura, and Ernst Meyer
Atom manipulation on an insulating surface at room temperature
Nature Communications | doi: 10.1038/ncomms5403