New conductivity mechanism of ions

Image: iStock
Image: iStock
Hydrogen is regarded as the energy source of the future: It is produced with solar power and can be used to generate heat and electricity in fuel cells. Empa researchers have now succeeded in decoding the movement of hydrogen ions in crystals - a key step towards more efficient energy conversion in the hydrogen industry of tomorrow. As charge carriers, electrons and ions play the leading role in electrochemical energy storage devices and converters such as batteries and fuel cells. Proton conductivity is crucial for the latter; protons, i.e. positively charged hydrogen ions, are formed from hydrogen, which is used to power the fuel cell. Empa physicist Artur Braun and Qianli Chen, a doctoral student at ETH Zurich, conducted neutron scattering experiments on the Swiss Spallation Neutron Source (SINQ) at the Paul Scherrer Institute (PSI) that document the mobility of protons in the crystal lattice. In the process, they observed that the proton movements in ceramic fuel cells obey far more complex laws than previously assumed: The movement of the protons takes place according to the so-called polaron model, as the researchers recently reported in the renowned. For a long time, the polaron theory developed by the Russian physicist and eventual Nobel Prize-winner Lev Davidovich Landau in 1933 only applied to electrons.
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